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A novel multifunctional composite based on reduced graphene oxide, poly-o-phenylenediamine and silicotungstic acid
Synthetic Metals ( IF 4.0 ) Pub Date : 2020-10-17 , DOI: 10.1016/j.synthmet.2020.116596
E. Yu. Pisarevskaya , I.I. Kolesnichenko , A.A. Averin , A.M. Gorbunov , O.N. Efimov

A novel electroactive composite based on silicotungstic acid (SiW), poly-о-phenylenediamine (PPD) and reduced form of graphene oxide (RGO) was prepared by electrochemical synthesis on a planar screen printed carbon electrode (SPCE) coated with graphene oxide (GO). The new material was shown to have expressed electrocatalytic activity for the example of electrochemical behavior of the p-benzoquinone/hydroquinone redox couple on the RGO-PPD-SiW-modified electrode. Unlike most composites containing heteropolyacid anions, RGO-PPD-SiW demonstrates its properties not only in an acid but also in a neutral saline solution. The potential cycling in a saline solution retains some cyclic voltammogram (CVA) peaks observed in 1 М H2SO4 environment. An addition of a local anesthetic of amide series (lidocaine, naropin, or chirocaine) to a saline solution was shown to change the CVA shape immediately. This example demonstrates that the novel composite may be further used in creating a sensor of planar design.



中文翻译:

一种基于氧化石墨烯,聚邻苯二胺和硅钨酸的新型多功能复合材料

通过在涂有氧化石墨烯(GO)的平面丝网印刷碳电极(SPCE)上进行电化学合成,制备了一种基于硅钨酸(SiW),聚对苯二胺(PPD)和还原形式的氧化石墨烯(RGO)的新型电活性复合材料。 )。以RGO-PPD-SiW修饰电极上的对苯醌/对苯二酚氧化还原对的电化学行为为例,该新材料已显示出具有电催化活性。与大多数包含杂多酸阴离子的复合材料不同,RGO-PPD-SiW不仅在酸中而且在中性盐水溶液中均显示出其特性。在盐溶液中的潜在循环保留了在1МH 2 SO 4中观察到的一些循环伏安图(CVA)峰环境。结果表明,在盐溶液中添加酰胺系列(利多卡因,萘丁肽或手性可卡因)的局部麻醉剂可立即改变CVA形状。该示例表明,该新型复合材料可进一步用于创建平面设计的传感器。

更新日期:2020-10-30
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