Abstract

New methods have been developed for the synthesis of previously unknown ω-(hexacyclo[9.2.1.0^2,7.0^3,5.0^4,8.0^9,13]tetradecan-10-exo-yloxy)alkan-1-ols and hexacyclo[9.2.1.0^2,7.0^3,5.0^4,8.0^9,13]tetradecan-10-exo-yl carboxylates by reactions of heptacyclo[8.4.0.0^2,12.0^3,8.0^4,6.0^5,9.0^11,13]tetradecane (binor-S) with α,ω-diols and organic acids in the presence of inorganic ionic liquids at 120–150°C for 6–8 h. The reactions involved regioselective cleavage of the cyclopropane C⁴–C⁵ bond of binor-S.

中文翻译：

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无机离子液体存在下Binor-S与α，ω-二醇和有机酸的反应

摘要

已经开发出用于合成先前未知的ω-（六环[9.2.1.0 ^2,7 .0 ^3,5 .0 ^4,8 .0 ^9,13 ] tetradecan-10- exo -yloxy）alkan-1-的新方法。醇和六环[9.2.1.0 ^2,7 0.0 ^3,5- 0.0 ^4,8 0.0 ^9,13 ]十四烷-10-外型-基由七环[反应的羧酸盐8.4.0.0 ^2,12 0.0 ^3,8 .0 ^4,6 .0 ^5,9 .0 ^11,13在无机离子液体存在下于120–150°C的温度下，将十四烷（binor-S）与α，ω-二醇和有机酸混合6-8小时。反应涉及 二元醇-S的环丙烷C ⁴ –C ⁵键的区域选择性裂解。