100th Anniversary of Macromolecular Science Viewpoint: Block Copolymers with Tethered Acid Groups: Challenges and Opportunities,ACS Macro Letters

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100th Anniversary of Macromolecular Science Viewpoint: Block Copolymers with Tethered Acid Groups: Challenges and Opportunities
ACS Macro Letters ( IF 5.1 ) Pub Date : 2020-10-16 , DOI: 10.1021/acsmacrolett.0c00629
Sejong Kang ₁ , Moon Jeong Park ₁

Affiliation

Scientific research on advanced polymer electrolytes has led to the emergence of all-solid-state energy storage/transfer systems. Early research began with acid-tethered polymers half a century ago, and research interest has gradually shifted to high-precision polymers with controllable acid functional groups and nanoscale morphologies. Consequently, various self-assembled acid-tethered block polymer morphologies have been produced. Their ion properties are profoundly affected by the multiscale intermolecular interactions in confinements. The creation of hierarchically organized ion/dipole arrangements inside the block copolymer nanostructures has been highlighted as a future method for developing advanced single-ion polymers with decoupled ion dynamics and polymer chain relaxation. Several emerging practical applications of the acid-tethered block copolymers have been explored to draw attention to the challenges and opportunities in developing state-of-the-art electrochemical systems.

中文翻译：

大分子科学100周年视点：束缚酸基嵌段共聚物：挑战与机遇

对先进聚合物电解质的科学研究导致了全固态能量存储/传输系统的出现。早期的研究始于半个世纪前的酸束缚聚合物，研究兴趣逐渐转向具有可控酸官能团和纳米级形貌的高精度聚合物。因此，已经产生了各种自组装酸束缚嵌段聚合物形态。它们的离子特性受到限制中多尺度分子间相互作用的深刻影响。在嵌段共聚物纳米结构内创建分层组织的离子/偶极子排列已被强调为开发具有解耦离子动力学和聚合物链松弛的先进单离子聚合物的未来方法。

更新日期：2020-11-17

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