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Determination of the δ2H values of high molecular weight lipids by high temperature GC coupled to isotope ratio mass spectrometry
Rapid Communications in Mass Spectrometry ( IF 2 ) Pub Date : 2020-10-17 , DOI: 10.1002/rcm.8983
Sabine K Lengger 1, 2 , Yuki Weber 3 , Kyle W R Taylor 4 , Sebastian H Kopf 5 , Robert Berstan 4 , Ian D Bull 1 , Jan-Peter Mayser 1 , William D Leavitt 6 , Jerome Blewett 1 , Ann Pearson 3 , Richard D Pancost 1, 7
Affiliation  

The hydrogen isotopic composition of lipids (δ2Hlipid) is widely used in food science and as a proxy for past hydrological conditions. Determining the δ2H values of large, well‐preserved triacylglycerides and other microbial lipids, such as glycerol dialkyl glycerol tetraether (GDGT) lipids, is thus of widespread interest but has so far not been possible due to their low volatility which prohibits analysis by traditional gas chromatography pyrolysis isotope ratio mass spectrometry (GC/P/IRMS).

中文翻译:

高温气相色谱联用同位素比质谱法测定高分子量脂质的 δ2H 值

脂质的氢同位素组成(δ 2 H脂质)广泛用于食品科学并作为过去水文条件的代表。因此,确定大的、保存完好的三酰基甘油酯和其他微生物脂质(如甘油二烷基甘油四醚 (GDGT) 脂质)的 δ 2 H 值受到广泛关注,但由于它们的低挥发性,这阻碍了分析传统的气相色谱热解同位素比质谱 (GC/P/IRMS)。
更新日期:2020-10-17
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