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Hydration characteristics of calcium sulfoaluminate (CSA) cement/Portland cement blended pastes
Journal of Building Engineering ( IF 6.7 ) Pub Date : 2020-10-16 , DOI: 10.1016/j.jobe.2020.101880
Solmoi Park , Yeonung Jeong , Juhyuk Moon , Namkon Lee

The hydration characteristics of calcium sulfoaluminate cement (CSA) and ordinary Portland cement (OPC) blended pastes incorporating calcium sulfate (CS¯) are investigated. The experimental characterization techniques were employed and complemented with thermodynamic calculations to provide in-depth understanding of the hydration of CSA/OPC blended system. The results showed that the hydration of C3S in the CSA/OPC blended pastes was significantly delayed in comparison with the sole OPC paste. The delayed hydration of C3S negatively affected the strength development of the CSA/OPC pastes. As the amount of CS¯ increases, the induction period occurring between the initial peak and the intermediate peak was extended, thus increasing the initial setting time. The addition of CS¯ to the CSA/OPC blends led to the two phenomena in the hydration of C4A3S¯, (1) retardation of C4A3S¯ hydration, and (2) formation of more ettringite after a few hours of hydration. The thermodynamic calculations indicated that the setting of the CSA/OPC blended system is mainly facilitated by hydration of C4A3S¯ and by the formation of ettringite, while the major strength-giving phase is C-S-H that originates from the hydration of C3S.



中文翻译:

硫铝酸钙(CSA)水泥/硅酸盐水泥掺和浆料的水化特性

硫铝酸钙水泥(CSA)和普通硅酸盐水泥(OPC)掺入硫酸钙(C的水泥)的水合特性小号¯)进行调查。采用了实验表征技术,并结合了热力学计算,以深入了解CSA / OPC混合体系的水合作用。结果表明,与唯一的OPC浆料相比,CSA / OPC混合浆料中C 3 S的水合作用明显延迟。C 3 S的延迟水合会对CSA / OPC浆料的强度发展产生负面影响。作为C量小号¯增大初始峰和中间峰之间的感应时间,从而延长了初始设定时间。C的加法小号¯CSA / OPC混合物的混合导致C 4 A 3水合的两种现象小号¯,(1)C 4 A 3的阻滞小号¯水合,以及(2)水合数小时后形成更多的钙矾石。热力学计算表明,CSA / OPC混合体系的设置主要是由于C 4 A 3的水合小号¯并且通过钙矾石的形成,而主要的赋予强度的阶段是CSH,其源自C 3 S的水合。

更新日期:2020-10-17
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