Abstract A promising method for the synthesis of a new class of macrocyclic phosphorus-containing tri- and diperoxides was developed. The method is based on catalytic ring transformation reactions of heptaoxadispiroalkanes, pentaoxacanes, and pentaoxadispiroalkanes with phenylphosphine followed by oxidation of the reaction mixture with H 2 O 2 .

中文翻译：

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在镧系元素催化剂存在下合成一类新的含三过氧化物和二过氧化物的大环磷

摘要 开发了一种合成新型大环含磷三过氧化物和二过氧化物的有前景的方法。该方法基于七氧二螺烷烃、五氧杂环己烷和五氧二螺烷烃与苯基膦的催化环转化反应，然后用H 2 O 2 氧化反应混合物。