Review on organosulfur materials for rechargeable lithium batteries,Materials Horizons

当前位置： X-MOL 学术 › Mater. Horiz. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Review on organosulfur materials for rechargeable lithium batteries
Materials Horizons ( IF 12.2 ) Pub Date : 2020-10-15 , DOI: 10.1039/d0mh01364a
Zulipiya Shadike ₁ , Sha Tan , Qin-Chao Wang , Ruoqian Lin , Enyuan Hu , Deyang Qu , Xiao-Qing Yang

Affiliation

Organic electrode materials have been considered as promising candidates for the next generation rechargeable battery systems due to their high theoretical capacity, versatility, and environmentally friendly nature. Among them, organosulfur compounds have been receiving more attention in conjunction with the development of lithium–sulfur batteries. Usually, organosulfide electrodes can deliver a relatively high theoretical capacity based on reversible breakage and formation of disulfide (S–S) bonds. In this review, we provide an overview of organosulfur materials for rechargeable lithium batteries, including their molecular structural design, structure related electrochemical performance study and electrochemical performance optimization. In addition, recent progress of advanced characterization techniques for investigation of the structure and lithium storage mechanism of organosulfur electrodes are elaborated. To further understand the perspective application, the additive effect of organosulfur compounds for lithium metal anodes, sulfur cathodes and high voltage inorganic cathode materials are reviewed with typical examples. Finally, some remaining challenges and perspectives of the organosulfur compounds as lithium battery components are also discussed. This review is intended to serve as general guidance for researchers to facilitate the development of organosulfur compounds.

中文翻译：

可充电锂电池用有机硫材料综述

有机电极材料因其高理论容量、多功能性和环境友好性而被认为是下一代可充电电池系统的有希望的候选材料。其中，有机硫化合物随着锂硫电池的发展受到越来越多的关注。通常，基于可逆断裂和二硫 (S-S) 键的形成，有机硫化物电极可以提供相对较高的理论容量。在这篇综述中，我们概述了用于可充电锂电池的有机硫材料，包括它们的分子结构设计、结构相关的电化学性能研究和电化学性能优化。此外，阐述了用于研究有机硫电极的结构和锂存储机制的先进表征技术的最新进展。为了进一步理解应用前景，本文通过典型实例回顾了有机硫化合物对锂金属负极、硫正极和高压无机正极材料的加成作用。最后，还讨论了有机硫化合物作为锂电池组件的一些剩余挑战和前景。本综述旨在作为研究人员促进有机硫化合物开发的一般指导。结合典型实例综述了硫正极和高压无机正极材料。最后，还讨论了有机硫化合物作为锂电池组件的一些剩余挑战和前景。本综述旨在作为研究人员促进有机硫化合物开发的一般指导。结合典型实例综述了硫正极和高压无机正极材料。最后，还讨论了有机硫化合物作为锂电池组件的一些剩余挑战和前景。本综述旨在作为研究人员促进有机硫化合物开发的一般指导。

更新日期：2020-11-27

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11