The solvent driven aggregation of porphyrin derivatives, covalently linked to a L- or D-prolinate enantiomer, results in the stereospecific formation of species featuring remarkable supramolecular chirality, as a consequence of reading and amplification of the stereochemical information stored in the proline-appended group. Spectroscopic, kinetic, and topographic SEM studies gave important information on the aggregation processes, and on the structures of the final chiral architectures. The results obtained may be the seeds for the construction of stereoselective sensors aiming at the detection, for example, of novel emergent pollutants from agrochemical, food, and pharmaceutical industry.

溶剂驱动的卟啉衍生物的聚集（共价连接至L-或D-脯氨酸的对映体）会导致立体显着形成具有显着超分子手性的物种，这是由于读取和扩增了脯氨酸附加组中存储的立体化学信息。光谱，动力学和形貌SEM研究提供了有关聚集过程和最终手性体系结构的重要信息。获得的结果可能是构建立体选择性传感器的种子，这些立体选择性传感器旨在检测例如农用化学，食品和制药行业的新型新兴污染物。