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Kinetic Analysis of the Hydrolysis of Pentose-1-Phosphates Through Apparent Nucleoside Phosphorolysis Equilibrium Shifts
ChemRxiv Pub Date : 2020-10-15
Felix Kaspar, Peter Neubauer, Anke Kurreck

Ask what an equilibrium can do for you:Hydrolysis of pentose-1-phosphates leads to an apparent increase of the equilibrium conversion in nucleoside phosphorolysis reactions. This information can be leveraged via equilibrium thermodynamics to determine the hydrolysis kinetics of in situ generated sugar phosphates, which are known to be elusive and difficult to quantify.

中文翻译:

通过表观核苷磷分解平衡位移对1-磷酸戊糖水解的动力学分析

问一个平衡能为您做什么:1-磷酸戊糖的水解导致核苷磷酸分解反应中平衡转化率的明显增加。可以通过平衡热力学来利用此信息来确定原位生成的糖磷酸酯的水解动力学,已知该糖磷酸酯难以捉摸且难以量化。
更新日期:2020-10-15
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