Chiral Spirocyclic Phosphoric Acids and Their Growing Applications,Chinese Journal of Chemistry

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Chiral Spirocyclic Phosphoric Acids and Their Growing Applications
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2020-10-14 , DOI: 10.1002/cjoc.202000446
Xufeng Lin ₁ , Lei Wang ₁ , Zhao Han ₁ , Zhouli Chen ₁

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Chiral spirocyclic phosphoric acids (SPAs) are introduced in 2010 and have been versatile catalysts capable of promoting a wide range of asymmetric organocatalytic reactions, such as multi‐component reactions, Friedel–Crafts reactions, Pictet–Spengler reactions, Fischer indolizations, cycloaddition reactions, desymmetrization reactions, dearomatization reactions, conjugate addition reactions and rearrangement reactions, etc. Moreover, a diverse range of applications in metal‐organic cooperative catalysis, organic photoredox catalysis, total synthesis, materials science and molecular recognition are beautifully illustrated. This account summarizes the past decade's advances in this field and highlights the selected but not comprehensive significant achievements.

中文翻译：

手性螺环磷酸及其应用前景

手性螺环磷酸（SPAs）于2010年推出，已成为通用催化剂，能够促进广泛的不对称有机催化反应，例如多组分反应，Friedel-Crafts反应，Pictet-Spengler反应，Fischer吲哚化，环加成反应，去对称化反应，脱芳香化反应，共轭加成反应和重排反应等。此外，在金属有机协作催化，有机光氧化还原催化，全合成，材料科学和分子识别中的各种应用也得到了很好的说明。该报告总结了该领域在过去十年中的进步，并重点介绍了一些精选但并非全面的重大成就。

更新日期：2020-10-14

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