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Highly efficient Imprinted Polymer Nanocomposites for photocatalytic desulfurization of real diesel fuel
Environmental Technology & Innovation ( IF 6.7 ) Pub Date : 2020-10-14 , DOI: 10.1016/j.eti.2020.101206
Asmaa S. Morshedy , Hager R. Ali , Amr A. Nada , Abdelrahman M. Rabie , Heba H. El-Maghrabi

The well-prepared imprinted nanocomposite polymer (MIP/AgPx) was used as a highly photo-active material in the oxidative desulfurization process. The synthesized nanocomposites were characterized using various analytical techniques including X-ray diffraction (XRD), UV diffuse reflectance spectroscopy (UV-DR), Fourier-transform infrared spectroscopy (FTIR), Photoluminescence spectroscopy (PL), and scanning electron microscope (SEM). The experimental parameters of the photo-desulfurization process, such as the source of radiations, the dosage of catalyst, reaction time, and addition of oxidizing agents such as hydrogen peroxide (H2O2)/acetic acid, were evaluated. The photo-degradation efficiency of dibenzothiophene (DBT, 450 ppm) was achieved 96% at room temperature in the presence of oxidizing agents with irradiation time 2h using xenon lamp (420 nm, 500 W). The removal efficiency enhanced to be 98% at the optimum conditions with high-quality diesel index: 96.17. The photocatalytic activity was attributed to the reduction of the recombination rate between electrons & holes and fast charge transfer. Furthermore, the MIP/AgP25 can be quickly recovered and reused by simple filtration for six times with a negligible decrease in the catalytic performance.



中文翻译:

用于实际柴油燃料光催化脱硫的高效印迹聚合物纳米复合材料

制备良好的压印纳米复合聚合物(MIP / AgPx)在氧化脱硫过程中用作高光敏材料。使用各种分析技术对合成的纳米复合材料进行表征,包括X射线衍射(XRD),紫外漫反射光谱(UV-DR),傅里叶变换红外光谱(FTIR),光致发光光谱(PL)和扫描电子显微镜(SEM) 。光脱硫过程的实验参数,例如辐射源,催化剂的用量,反应时间以及氧化剂的添加,例如过氧化氢(H2Ø2)/乙酸进行评估。实现了二苯并噻吩的光降解效率(DBT,450 ppm)在室温下,在存在氧化剂的情况下,使用氙气灯(420 nm,500 W)在2h的照射时间下达到96%。在最佳条件下,使用高质量柴油指数:96.17,去除效率提高到98%。光催化活性归因于电子与空穴之间的重组率降低和电荷快速转移。此外,MIP / AgP25可以通过简单过滤快速回收并重复使用六次,而催化性能却可以忽略不计。

更新日期:2020-10-15
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