Tetra(p-tolyl)antimony 2,4,6-trichlorophenoxide p-Tol4SbOC6H2Cl3-2,4,6 (1) and tetra(p-tolyl)antimony 3,4,5-trifluorobenzoate p-Tol4SbOС(O)C6H2F3-3,4,5 (2) are synthesized by the interaction of penta(p-tolyl)antimony with equimolar amounts of 2,4,6-trichlorophenol and 3,4,5-trifluorobenzoic acid in a benzene solution. Compounds 1 and 2 are also obtained by ligand redistribution reactions between penta(p-tolyl)antimony and symmetric antimony derivatives p-Tol3SbХ2. The crystal structures and structural features of compounds 1 and 2, in which antimony atoms have a trigonal bipyramidal coordination of substituents with axially located oxygen-containing ligands, are determined by single crystal X-ray diffraction.

中文翻译：

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四（对甲苯基）锑 2,4,6-三氯苯氧化物和 3,4,5-三氟苯甲酸盐的晶体结构研究

四（对甲苯基）锑 2,4,6-三氯苯氧化物 p-Tol4SbOC6H2Cl3-2,4,6 (1) 和四（对甲苯基）锑 3,4,5-三氟苯甲酸盐 p-Tol4SbOС(O)C6H2F3-3 ,4,5 (2) 是通过五（对甲苯基）锑与等摩尔量的 2,4,6-三氯苯酚和 3,4,5-三氟苯甲酸在苯溶液中的相互作用合成的。化合物 1 和 2 也可以通过五（对甲苯基）锑和对称锑衍生物 p-Tol3SbХ2 之间的配体再分配反应获得。化合物 1 和 2 的晶体结构和结构特征由单晶 X 射线衍射确定，其中锑原子具有取代基与轴向定位的含氧配体的三角双锥配位。