A Monocationic Zn(II) Acetate Complex of a Chiral Bisamidine Dioxolane Ligand, Naph-diPIM-dioxo-R, for the Asymmetric 1,3-Dipolar Cycloaddition of Tridentate α-Substituted α-Imino Esters and Acrylates to Multi-substituted Prolines: Importance of an n-π* Interaction for High Enantioselectivity,Bulletin of the Chemical Society of Japan

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A Monocationic Zn(II) Acetate Complex of a Chiral Bisamidine Dioxolane Ligand, Naph-diPIM-dioxo-R, for the Asymmetric 1,3-Dipolar Cycloaddition of Tridentate α-Substituted α-Imino Esters and Acrylates to Multi-substituted Prolines: Importance of an n-π* Interaction for High Enantioselectivity
Bulletin of the Chemical Society of Japan ( IF 3.3 ) Pub Date : 2021-01-15 , DOI: 10.1246/bcsj.20200266
Indukuru Naga Chaithanya Kiran ₁ , Kazuki Fujita ₂ , Kazuki Kobayashi ₂ , Shinji Tanaka ₁ , Masato Kitamura ₂

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A monocationic Zn(II) acetate complex of a C2-chiral bisamidine-type sp2N bidentate ligand (LR) possessing two dioxolane oxygen n orbitals in the reaction site catalyzes, without the use of an exte...

中文翻译：

手性双脒二氧戊环配体 Naph-diPIM-dioxo-R 的单阳离子醋酸锌配合物，用于三齿 α-取代的 α-亚氨基酯和丙烯酸酯与多取代脯氨酸的不对称 1,3-偶极环加成反应：重要性高对映选择性的 n-π* 相互作用

在反应位点具有两个二氧戊环氧 n 轨道的 C2-手性双脒型 sp2N 双齿配体 (LR) 的单阳离子 Zn(II) 醋酸盐络合物催化，无需使用外加...

更新日期：2021-01-15

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