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AgO/MgO/FeO@Si3N4 nanocomposite with robust adsorption capacity for tetracycline antibiotic removal from aqueous system
Advanced Powder Technology ( IF 5.2 ) Pub Date : 2020-10-12 , DOI: 10.1016/j.apt.2020.09.006
Gaurav Sharma , Sangeeta Bhogal , Amit Kumar , Mu. Naushad , Shweta Sharma , Tansir Ahamad , Florian J. Stadler

Present study has been designed to govern the usage of nanocomposite of Si3N4 with trimetallic oxide nanoparticles of Ag, Mg and Fe (AgO/MgO/FeO@Si3N4) for the tetracycline (TC) removal from aqueous solution. Characterization techniques such as SEM, TEM, XRD, FTIR, XPS and BET were employed for analysing the successful fabrication of AgO/MgO/FeO@Si3N4 nanocomposite. Adsorption process has been found to be dependent upon the surface properties of AgO/MgO/FeO@Si3N4 nanocomposite (such as charge, functionality, etc), concentration of TC, solution pH and contact time. As determined from the isotherm studies, surface of AgO/MgO/FeO@Si3N4 nanocomposite has been found to be energetically heterogeneous in nature as the data fitted well to Freundlich isotherm. Maximum adsorption capacity of AgO/MgO/FeO@Si3N4 nanocomposite has been found to be 172.41 mg/g. Pseudo-second order kinetic model successfully explained the rate studies of TC adsorption. Also, reusability study of AgO/MgO/FeO@Si3N4 nanocomposite has also been carried out. In short, the present study could determine an effective way for the removal of toxic pollutants from the wastewater system.



中文翻译:

AgO / MgO / FeO @ Si3N4纳米复合材料具有强大的吸附能力,可从水系统中去除四环素类抗生素

目前的研究已经设计为控制Si 3 N 4纳米复合物与Ag,Mg和Fe的三金属氧化物纳米粒子(AgO / MgO / FeO @ Si 3 N 4)的使用,以从水溶液中去除四环素(TC)。采用SEM,TEM,XRD,FTIR,XPS和BET等表征技术对AgO / MgO / FeO @ Si 3 N 4纳米复合材料的成功制备进行了分析。已经发现吸附过程取决于AgO / MgO / FeO @ Si 3 N 4纳米复合材料的表面性质(例如电荷,官能度等),TC浓度,溶液pH和接触时间。根据等温线研究确定,AgO / MgO / FeO @ Si的表面已经发现3 N 4纳米复合材料在能量上是异质的,因为该数据非常适合Freundlich等温线。发现AgO / MgO / FeO @ Si 3 N 4纳米复合材料的最大吸附容量为172.41 mg / g。伪二级动力学模型成功地解释了TC吸附速率的研究。此外,还进行了AgO / MgO / FeO @ Si 3 N 4纳米复合材料的可重复使用性研究。简而言之,本研究可以确定从废水系统中去除有毒污染物的有效方法。

更新日期:2020-10-12
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