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Non-thermal plasma-assisted catalytic CO 2 conversion over Zn-TCPP 2D catalyst
Adsorption ( IF 3.0 ) Pub Date : 2020-03-17 , DOI: 10.1007/s10450-020-00222-7
Marek Wiśniewski , Artur P. Terzyk

There is still a growing interest in CO2 conversion into useful compounds. Plasma technology is a highly promising alternative due to its non-equilibrium nature, crucial for CO2 dissociation processes. In this study we present, the non-thermal plasma-assisted catalytic CO2 reduction to CO on 2D Zn-containing paddle wheel structures based on TCPP. The catalytic efficiency of this MOF material is shown to be high. The experimental data from HRTEM, adsorption and FTIR analyses lead to the simplified model mechanism of this process.



中文翻译:

Zn-TCPP 2D催化剂上非热等离子体辅助催化CO 2转化

对CO 2转化为有用化合物的兴趣仍在增长。等离子体技术由于其非平衡性质而成为非常有前途的替代方法,这对于CO 2分解过程至关重要。在这项研究中,我们目前基于TCPP将非热等离子体辅助的CO 2催化还原为2D含锌桨轮结构上的CO。该MOF材料的催化效率显示为高。来自HRTEM,吸附和FTIR分析的实验数据导致该过程的简化模型机制。

更新日期:2020-03-17
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