By the methods of wide-angle X-ray diffraction and small-angle X-ray scattering, we study the specific features of the structural organization of pectin–Ag0–P4VP nanocomposites obtained under the action of constant electric fields. It is shown that, in the process of chemical reduction of Ag+ ions in polyelectrolyte–metal complexes, under the action of electric fields, we observe the formation of nanocomposites with higher contents of metallic silver than in the absence of the field. By the method of thermomechanical analysis, it is demonstrated that these materials have a much higher temperature of vitrification, a lower temperature of transition into the viscous-flow state, and a higher susceptibility to relative deformation.

中文翻译：

---

在电场作用下通过还原聚电解质-金属络合物中的 Ag+ 离子形成含银聚合物纳米复合材料

通过广角X射线衍射和小角X射线散射的方法，我们研究了在恒定电场作用下获得的果胶-Ag0-P4VP纳米复合材料的结构组织的具体特征。结果表明，在聚电解质-金属络合物中Ag+离子的化学还原过程中，在电场的作用下，我们观察到形成的纳米复合材料的金属银含量高于没有电场的情况。通过热机械分析的方法表明，这些材料具有更高的玻璃化温度，更低的转变为粘流状态的温度，以及更高的相对变形敏感性。