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Enhancement of optical and mechanical properties of sodium silicate glasses using zirconia
Optical and Quantum Electronics ( IF 3.3 ) Pub Date : 2020-10-01 , DOI: 10.1007/s11082-020-02575-3
E. A. Abdel Wahab , Kh. S. Shaaban , El Sayed Yousef

Ternary glass system with the composition of 50Na2O–(50–x) SiO2–x ZrO2, (0 ≤ x ≤ 20 mol %) has been prepared by melt quenching method. The structure changes of these glasses are studied by FT-IR spectra. The mechanical properties have been related to the results of FT-IR spectra. X-ray diffractograms showing the amorphous nature of these glasses. The mechanical properties of these glasses are studied and their elastic-moduli have been estimated. It was noted that the elastic-moduli, density and some physical properties of these samples are increased. Optical feature spectra are recorded at room temperature. The dispersion parameters as refractive index (n) and extinction coefficient (k) are determined in the wavelength range of 300–2500 nm. Energy band gap and Urbach energy with indirect allowed transitions are estimated using Tauc model. The dielectric constant in term of real and imaginary parts are investigated. Other physical parameters like skin depth, cut-off wavelength, dissipation factor, optical and electrical conductivities are calculated as well.

中文翻译:

使用氧化锆提高硅酸钠玻璃的光学和机械性能

由 50Na2O–(50–x) SiO2–x ZrO2 (0 ≤ x ≤ 20 mol %) 组成的三元玻璃体系已通过熔融淬火方法制备。通过 FT-IR 光谱研究了这些玻璃的结构变化。机械性能与 FT-IR 光谱的结果有关。X 射线衍射图显示了这些玻璃的无定形性质。研究了这些玻璃的机械性能并估计了它们的弹性模量。注意到这些样品的弹性模量、密度和一些物理性质增加。在室温下记录光学特征光谱。色散参数如折射率 (n) 和消光系数 (k) 在 300-2500 nm 的波长范围内确定。使用 Tauc 模型估计带间接允许跃迁的能带隙和 Urbach 能量。研究了实部和虚部的介电常数。其他物理参数,如趋肤深度、截止波长、耗散因数、光导率和电导率等也计算在内。
更新日期:2020-10-01
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