Tetraamminecopper Perchlorate (TACP): Explosive Properties,Propellants, Explosives, Pyrotechnics

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Tetraamminecopper Perchlorate (TACP): Explosive Properties
Propellants, Explosives, Pyrotechnics ( IF 1.7 ) Pub Date : 2020-10-08 , DOI: 10.1002/prep.202000131
Ondřej Vodochodský ₁ , Martin Künzel ₂ , Robert Matyáš ₁ , Jinřich Kučera ₁ , Jiri Pachman ₁

Affiliation

Tetraamminecopper perchlorate (TACP) is one of the most interesting explosive copper perchlorate‐ammonia complexes. Despite the fact that this complex has been known for more than 100 years there is very little information in the literature about its detonation parameters. Impact sensitivity of TACP is slightly higher than that for PETN while friction sensitivity is between those for PETN and RDX. Detonation velocity for infinite diameter is 3230 m s⁻¹ (density 0.9 g cm⁻³). Critical diameter of TACP is low – less than 2 mm. Based on the heat of combustion measurement the previously published erroneous enthalpy of formation was corrected to −496 kJ mol⁻¹. Detonation heat of TACP is 4322 kJ kg⁻¹ and Gurney velocity is 1536 m s⁻¹. Experimentally measured detonation parameters of TACP were also compared with theoretically calculated values by the EXPLO5 code.

中文翻译：

四氨合高氯酸铜（TACP）：爆炸特性

四氨合高氯酸铜（TACP）是最有趣的爆炸性高氯酸铜-氨络合物之一。尽管已经知道这种复合物已有100多年的历史了，但文献中关于其爆炸参数的信息很少。TACP的冲击敏感性略高于PETN，而摩擦敏感性介于PETN和RDX之间。无限直径的爆震速度为3230 m s ^-1（密度0.9 g cm ^-3）。TACP的临界直径很低–小于2 mm。基于燃烧热的测量，先前公开的错误的形成焓被校正为-496 kJ mol ^-1。TACP的爆炸热为4322 kJ kg ^-1，格尼速度为1536 m s^-1。还通过EXPLO5代码将实验测得的TACP爆震参数与理论计算值进行了比较。

更新日期：2020-10-08

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