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Exchange Interactions Drive Supramolecular Chiral Induction in Polyaniline (Small Methods 10/2020)
Small Methods ( IF 10.7 ) Pub Date : 2020-10-07 , DOI: 10.1002/smtd.202070038
Suryakant Mishra 1 , Anup Kumar 2 , Munuswamy Venkatesan 2 , Laura Pigani 3 , Luca Pasquali 4, 5, 6 , Claudio Fontanesi 4
Affiliation  

In article number 2000617, Claudio Fontanesi and co‐workers study the camphor sulfonic acid induction of chirality on the supermolecular structure of electropolymerized aniline. The emergence of chirality is also associated to spin filtering properties of the chiral polymer, revealed by conducting probe atomic force microscopy in the presence of a magnetic field. Theoretical results suggest that the chiral induction is due to exchange interaction energy.
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中文翻译:

交换相互作用驱动聚苯胺中的超分子手性诱导(小方法10/2020)

Claudio Fontanesi及其同事在编号2000617的文章中研究了樟脑磺酸对电聚合苯胺的超分子结构的手性的诱导作用。手性的出现还与手性聚合物的自旋过滤性能有关,这通过在磁场存在下进行探针原子力显微镜检查来揭示。理论结果表明,手性诱导归因于交换相互作用能。
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更新日期:2020-10-07
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