Reversible Reductive Elimination in Aluminum(II) Dihydrides,Angewandte Chemie International Edition

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Reversible Reductive Elimination in Aluminum(II) Dihydrides
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-10-06 , DOI: 10.1002/anie.202011418
Rosalyn L. Falconer ₁ , Gary S. Nichol ₁ , Ivan V. Smolyar ₁ , Scott L. Cockroft ₁ , Michael J Cowley ₂

Affiliation

Oxidative addition and reductive elimination are defining reactions of transition‐metal organometallic chemistry. In main‐group chemistry, oxidative addition is now well‐established but reductive elimination reactions are not yet general in the same way. Herein, we report dihydrodialanes supported by amidophosphine ligands. The ligand serves as a stereochemical reporter for reversible reductive elimination/oxidative addition chemistry involving Al^I and Al^III intermediates.

中文翻译：

氢化铝（II）中的可逆还原消除

氧化加成和还原消除是过渡金属有机金属化学反应的定义。在主族化学中，现在已经确定了氧化加成反应，但是还原消除反应还没有以相同的方式进行。在本文中，我们报道了由氨基膦配体支持的二氢重氮。该配体用作涉及Al ^I和Al ^III中间体的可逆还原消除/氧化加成化学的立体化学报告分子。

更新日期：2020-10-06

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