Developing highly efficient energy storage technologies is of great significance as the strong support for the utilization of renewable and sustainable energy. Sodium-ion batteries (SIBs) and potassium-ion batteries (KIBs) have attracted considerable attentions as the new generation metal-ion batteries due to the abundance natural reserve and cost-effective merits of Na and K. Phosphorus is viewed as a promising candidate among various anode materials while its poor cycling stability and sluggish electrochemical reaction dynamics caused by huge volume variation and inherently low electronic conductivity greatly limit its practical use for energy storage devices. Compositing by introducing a suitable second component has been proposed as an effective strategy to potentially resolve those issues. Herein, the research progress of phosphorus composite anodes for SIBs/KIBs is reviewed. We firstly summarized the primary modulation methods of anode materials with the working mechanisms of red/black phosphorus (RP/BP) for SIBs/KIBs introduced. The compositing strategies and materials were then reviewed for RP and BP separately from carbonaceous, metallic and organic polymer substrates, respectively. Finally, the challenges and opportunities of RP/BP composites in the development of SIBs/KIBs were presented with the hope to provide some inspirations for the design and fabrication of advanced SIBs/KIBs energy storage systems.

作为对可再生能源和可持续能源利用的有力支持，发展高效的储能技术具有重要意义。钠离子电池（SIBs）和钾离子电池（KIBs）作为新一代金属离子电池已吸引了相当多的关注，这归功于Na和K的丰富自然储备以及具有成本效益的优点。磷被认为是有前途的候选人然而，由于其巨大的体积变化和固有的低电子电导率，其循环稳定性差和电化学反应动力学缓慢，大大限制了其在储能装置中的实际应用。已经提出通过引入合适的第二组件来进行合成作为解决这些问题的有效策略。在这里 综述了SIBs / KIBs用磷复合阳极的研究进展。我们首先介绍了阳极材料的主要调制方法，并介绍了用于SIBs / KIBs的红/黑磷（RP / BP）的工作机理。然后分别从碳质，金属和有机聚合物基质分别审查了RP和BP的合成策略和材料。最后，提出了RP / BP复合材料在SIBs / KIBs开发中的挑战和机遇，希望为高级SIBs / KIBs储能系统的设计和制造提供一些启发。然后分别从碳质，金属和有机聚合物基质分别审查了RP和BP的合成策略和材料。最后，提出了RP / BP复合材料在SIBs / KIBs开发中的挑战和机遇，希望为高级SIBs / KIBs储能系统的设计和制造提供一些启发。然后分别从碳质，金属和有机聚合物基质分别审查了RP和BP的合成策略和材料。最后，提出了RP / BP复合材料在SIBs / KIBs开发中的挑战和机遇，希望为高级SIBs / KIBs储能系统的设计和制造提供一些启发。