Electrochemical Applications of Ferrocene‐Based Coordination Polymers,ChemPlusChem

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Electrochemical Applications of Ferrocene‐Based Coordination Polymers
ChemPlusChem ( IF 3.0 ) Pub Date : 2020-10-05 , DOI: 10.1002/cplu.202000584
Mao-Lin Hu ₁ , Mahsa Abbasi-Azad ₂ , Behnam Habibi ₂ , Farzaneh Rouhani ₂ , Hamed Moghanni-Bavil-Olyaei ₂ , Kuan-Guan Liu ₃ , Ali Morsali ₄

Affiliation

Ferrocene and its derivatives, especially ferrocene‐based coordination polymers (Fc‐CPs), offer the benefits of high thermal stability, two stable redox states, fast electron transfer, and excellent charge/discharge efficiency, thus holding great promise for electrochemical applications. Herein, we describe the synthesis and electrochemical applications of Fc‐CPs and reveal how the incorporation of ferrocene units into coordination polymers containing other metals results in unprecedented properties. Moreover, we discuss the usage of Fc‐CPs in supercapacitors, batteries, and sensors as well as further applications of these polymers, for example in electrocatalysts, water purification systems, adsorption/storage systems.

中文翻译：

二茂铁基配位聚合物的电化学应用

二茂铁及其衍生物，特别是二茂铁基配位聚合物（Fc-CPs）具有高热稳定性，两个稳定的氧化还原态，快速的电子转移和出色的充放电效率等优点，因此在电化学应用中具有广阔的前景。本文中，我们描述了Fc-CP的合成和电化学应用，并揭示了将二茂铁单元并入含其他金属的配位聚合物中如何产生前所未有的性能。此外，我们讨论了Fc-CP在超级电容器，电池和传感器中的使用以及这些聚合物的进一步应用，例如在电催化剂，水净化系统，吸附/存储系统中。

更新日期：2020-11-03

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