Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry,Angewandte Chemie International Edition

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Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-10-05 , DOI: 10.1002/anie.202010963
Thomas X Gentner ₁ , Robert E Mulvey ₁

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Organolithium compounds have been at the forefront of synthetic chemistry for over a century, as they mediate the synthesis of myriads of compounds that are utilised worldwide in academic and industrial settings. For that reason, lithium has always been the most important alkali metal in organometallic chemistry. Today, that importance is being seriously challenged by sodium and potassium, as the alkali‐metal mediation of organic reactions in general has started branching off in several new directions. Recent examples covering main‐group homogeneous catalysis, stoichiometric organic synthesis, low‐valent main‐group metal chemistry, polymerization, and green chemistry are showcased in this Review. Since alkali‐metal compounds are often not the end products of these applications, their roles are rarely given top billing. Thus, this Review has been written to alert the community to this rising unifying phenomenon of “alkali‐metal mediation”.

中文翻译：

碱金属介导：主族有机金属化学中的多种应用

一个多世纪以来，有机锂化合物一直处于合成化学的前沿，因为它们介导了全世界学术和工业环境中使用的无数化合物的合成。因此，锂一直是有机金属化学中最重要的碱金属。如今，这种重要性正受到钠和钾的严重挑战，因为一般有机反应的碱金属介导已经开始向几个新的方向分支。本综述展示了最近的例子，涵盖主族均相催化、化学计量有机合成、低价主族金属化学、聚合和绿色化学。由于碱金属化合物通常不是这些应用的最终产品，因此它们的作用很少受到重视。因此，撰写这篇评论是为了提醒社会注意这种日益兴起的“碱金属调解”统一现象。

更新日期：2020-10-05

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