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Fixed-bed adsorption performance and empirical modelling of cadmium removal using adsorbent prepared from the cyanobacterium Aphanothece sp cultivar
Environmental Technology & Innovation ( IF 6.7 ) Pub Date : 2020-10-03 , DOI: 10.1016/j.eti.2020.101194
Awalina Satya , Ardiyan Harimawan , Gadis Sri Haryani , M.A.H. Johir , Luong N. Nguyen , Long D. Nghiem , Saravanamuthu Vigneswaran , Huu Hao Ngo , Tjandra Setiadi

Water contamination by cadmium (Cd), which is a toxic heavy metal widely used in many industrial processes, is a pervasive environmental problem. This study investigated the removal of Cd by dry cyanobacterium Aphanothece sp cultivar in adsorption columns The effect of inlet Cd concentrations (1.00 – 4.85mg/L), flow rates (0.30-0.60 L/h) and bed height (4.6 -7.2 cm) on the breakthrough characteristics of the adsorption column was investigated. The maximum adsorption capacity and efficiency were found to be 8.20 mg/g and 89.07 %, respectively with a flow rate of 0.60 L/h and 4.85 mg/L inlet concentration of Cd. The fixed bed adsorption data were fitted to three well known fixed bed empirical models namely Thomas, Adam-Bohart and Yoon-Nelson. The experimental results well fitted with the models mentioned above with R2 of greater than 0.98 at different conditions. The regeneration efficiency of benthic cyanobacterium Aphanothece sp cultivar based adsorbent was studied using 0.1 M HCl. Repetitive adsorption-regeneration experiment show that, at the end of the fifth cycle, the desorption efficiency decreased by 21%. Thus, further research is necessary to improve the reusability of dried biomass of cyanobacterium Aphanothece sp adsorbent.



中文翻译:

固定床吸附性能和使用蓝藻Aphanothece sp品种制备的吸附剂去除镉的经验模型

镉(Cd)是一种有毒的重金属,在许多工业过程中广泛使用,对水的污染是一个普遍存在的环境问题。本研究研究了干燥蓝藻Aphanothece sp对镉的去除吸附塔中的品种研究了入口Cd浓度(1.00 – 4.85mg / L),流速(0.30-0.60 L / h)和床高(4.6 -7.2 cm)对吸附塔穿透特性的影响。发现最大吸附容量和效率分别为8.20 mg / g和89.07%,流速为0.60 L / h和4.85 mg / L Cd入口浓度。将固定床吸附数据拟合到三个众所周知的固定床经验模型,即Thomas,Adam-Bohart和Yoon-Nelson。实验结果与上述模型在不同条件下的R 2均大于0.98完全吻合。底栖蓝细菌Aphanothece sp的再生效率使用0.1 M HCl研究了基于品种的吸附剂。重复吸附-再生实验表明,在第五个循环结束时,解吸效率降低了21%。因此,有必要进行进一步的研究以改善蓝藻Aphanothece sp吸附剂的干燥生物质的可重复使用性。

更新日期:2020-10-04
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