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Revisiting and enhancing electrochemical properties of SnO 2 as anode for sodium-ion batteries
Journal of Solid State Electrochemistry ( IF 2.6 ) Pub Date : 2020-10-02 , DOI: 10.1007/s10008-020-04779-9
Rasmita Biswal , Debasis Nayak , S. Janakiraman , N. Vijay Prakash Chaudhary , Sudipto Ghosh , Venimadhav Adyam

The tin oxide (SnO2) thin films have been prepared by the pulsed laser deposition (PLD) at deposition temperatures (Td) ranging from 300 to 500 °C with different morphologies and studied as anode for sodium-ion battery. The microstructural evolutions of the thin films are investigated by various techniques which reveal a pure SnO2 phase. The crystallinity of the thin film deposited at 300 °C shows partial amorphous characteristics. Among all the samples, SnO2 thin film deposited at 300 °C exhibits superior electrochemical performance. The films at 300 °C display a high specific capacity of 488 mAh g−1 (at 20 mA g−1) after 50 cycles and a coulombic efficiency of 96% after 200 cycles at 130 mA g−1 (voltage window of 0.01 V to 2.0 V). The achieved high specific capacity can be credited to sodium (Na) storage mechanisms of SnO2, which are both (1) conversion of SnO2 to Sn nanocrystals and followed by (2) alloying of Na and Sn.



中文翻译:

回顾和增强SnO 2作为钠离子电池阳极的电化学性能

氧化锡(SnO 2)薄膜是通过脉冲激光沉积(PLD)在300到500°C的沉积温度(T d)下制备的,具有不同的形貌,并被用作钠离子电池的阳极。通过揭示纯SnO 2相的各种技术研究了薄膜的微观结构演变。在300℃下沉积的薄膜的结晶度显示出部分非晶态特性。在所有样品中,在300°C沉积的SnO 2薄膜表现出优异的电化学性能。300°C时的薄膜显示出488 mAh g -1的高比容量(20 mA g -1时))50个循环后,在130 mA g -1(0.01 V至2.0 V的电压窗口)下200个循环后的库仑效率为96%。所获得的高比容量可以归因于SnO 2的钠(Na)储存机制,这既是(1)将SnO 2转化为Sn纳米晶体,又是(2)Na和Sn合金化。

更新日期:2020-10-02
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