Studies on Interactions of 5,6-Diaryl-3-(Quinolin-2-YL)-1,2,4-Triazines with Arynes: A TM-Free One-Step Approach to 2-(3,4-Diarylisoquinolin-1-YL)Quinolines,Polycyclic Aromatic Compounds

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Studies on Interactions of 5,6-Diaryl-3-(Quinolin-2-YL)-1,2,4-Triazines with Arynes: A TM-Free One-Step Approach to 2-(3,4-Diarylisoquinolin-1-YL)Quinolines
Polycyclic Aromatic Compounds ( IF 2.4 ) Pub Date : 2020-10-01 , DOI: 10.1080/10406638.2020.1823858
Sravya Gundala ₁ , Albert F. Khasanov _{1,

2} , Dmitry S. Kopchuk _{1,

2} , Ekaterina S. Starnoskaya _{1,

2} , Yaroslav K. Shtaitz ₁ , Alexey P. Krinochkin _{1,

2} , Eugeny B. Gorbunov ₂ , Grigory V. Zyryanov _{1,

2} , Venkatapuram Padmavathi ₃ , Oleg N. Chupakhin _{1,

2}

Affiliation

Abstract

Interactions of 5,6-diaryl-3-(quinolin-2-yl)-1,2,4-triazines with arynes are studied. 2-(3,4-Diarylisoqunolin-1-yl)quinolines are obtained in up to 65% yield via the inverse-demand Diels-Alder reaction between 5,6-diaryl-3-(quinolone-2-yl)-1,2,4-triazines and benzyne, generated in situ.

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