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Auto‐catalytic production of eugenyl acetate and eugenyl butyrate using microwave radiation: a kinetic and mechanism‐related approach
Journal of Chemical Technology and Biotechnology ( IF 2.8 ) Pub Date : 2020-10-01 , DOI: 10.1002/jctb.6583
Malihe Keramat 1 , Mohammad‐Taghi Golmakani 1 , Erwann Durand 2, 3 , Pierre Villeneuve 2, 3 , Seyed Mohammad Hashem Hosseini 1
Affiliation  

Applications of chemical and enzymatic methods of esterification have been limited by low selectivity of chemical catalysts and low productivity and high cost of enzymes. The objective of this study was to produce eugenol esters with high productivity and selectivity using a microwave technique without adding any catalyst or solvent. Specific focus was given to reaction temperature and molar ratio to establish the kinetics and mechanism of eugenol auto‐catalytic acylation using microwave radiation.

中文翻译:

微波辐射自动催化生产乙酸丁二烯酯和丁酸丁二烯酯:动力学和机理相关的方法

化学和酶促酯化方法的应用受到化学催化剂的低选择性和酶的低生产率和高成本的限制。这项研究的目的是使用微波技术在不添加任何催化剂或溶剂的情况下以高生产率和选择性生产丁子香酚酯。特别关注反应温度和摩尔比,以建立使用微波辐射的丁香酚自催化酰化反应的动力学和机理。
更新日期:2020-10-01
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