This paper provides a set of comprehensive guidelines for the use of dynamic column breakthrough experiments to measure single and multi-component equilibria and kinetics. Recommendations are made for the design of the experimental rig, experimental procedures, and data processing methods to minimize errors and increase data reliability. Designing experiments to identify the transport mechanism, and quantitatively interpreting the breakthrough responses via modeling and optimization are also enumerated. Results reported in relevant published literature are also used to illustrate the ideas and concepts.

中文翻译：

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动态柱突破实验，用于测量吸附平衡和动力学

本文为使用动态色谱柱突破实验测量单组分和多组分平衡与动力学提供了一套综合指南。为实验装置，实验程序和数据处理方法的设计提出了建议，以最大程度地减少错误并提高数据可靠性。还列举了设计实验以识别运输机制，并通过建模和优化来定量解释突破反应。相关出版文献中报道的结果也用于说明这些想法和概念。