Journal of the Taiwan Institute of Chemical Engineers ( IF 5.5 ) Pub Date : 2020-09-29 , DOI: 10.1016/j.jtice.2020.09.018 Xuan Nui Pham , Hoa Thi Nguyen , Tuyet Nhung Pham , T.-Thanh-Bao Nguyen , Manh B. Nguyen , Van Thi-T. Tran , Huan V. Doan
A novel oxygen-doped graphitic carbon nitride and zeolite (H-ZSM-5) composite (O–g–C3N4/H-ZSM-5) was synthesized using hydrogen peroxide and urea as the oxygen and g–C3N4 precursors, respectively, and perlite as the zeolite source, via calcination at 550°C. BET N2 adsorption-desorption analysis verified that the 40%O–g–C3N4/H-ZSM-5 composite had a high surface area of 259.13 m2/g with mesopores and micropores, and X-ray photoelectron spectroscopy (XPS) confirmed the existence of the O atom in the g–C3N4 framework. The obtained O–g–C3N4/H-ZSM-5 catalyst showed excellent photocatalytic performance for the photodegradation of RR 195, approximately 96.6% with a high rate constant of 0.1167min−1 under solar light irradiation without the use of H2O2. It also exhibited remarkable stability and long-term recyclability, with the photodegradation efficiency of RR 195 above 91%. In conclusion, the O–g–C3N4/H-ZSM-5 composite photocatalyst is suitable for numerous applications in the field of the photocatalytic degradation of organic pollutants.
中文翻译:
H-ZSM-5沸石锚定的O掺杂的g-C 3 N 4的绿色合成,用于在太阳光下降解活性红195(RR 195)
以过氧化氢和尿素为氧和g - C 3 N的合成了一种新型的氧掺杂石墨氮化碳和沸石(H - ZSM-5)复合材料(O - g - C 3 N 4 / H - ZSM-5)。通过550煅烧分别得到4种前体和珍珠岩作为沸石源℃。BET N 2吸附-解吸分析证实,具有中孔和微孔的40%O – g – C 3 N 4 / H - ZSM-5复合材料的高表面积为259.13 m 2 / g,并且通过X射线光电子能谱( XPS)证实了g – C 3 N 4骨架中O原子的存在。所得的O -克- C ^ 3 Ñ 4 / H -ZSM-5催化剂对RR 195的光降解表现出优异的光催化性能,约为96.6%,其高速率常数为0.1167在不使用H 2 O 2的太阳光照射下,min -1。它还具有出色的稳定性和长期可回收性,RR 195的光降解效率超过91%。总之,O – g – C 3 N 4 / H - ZSM-5复合光催化剂适用于有机污染物的光催化降解领域中的许多应用。