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Hydrocracking and hydrotreating reaction kinetics of heavy oil in CSTR using a dispersed catalyst
Journal of Petroleum Science and Engineering Pub Date : 2020-09-28 , DOI: 10.1016/j.petrol.2020.107997
Hung Hai Pham , Kwang Ho Kim , Kang Seok Go , Nam Sun Nho , Woohyun Kim , Eun Hee Kwon , Ryu Ho Jung , Young-il Lim , Suk Hyun Lim , Dung Anh Pham

A kinetic model for the slurry-phase hydrocracking of vacuum residue was proposed under conditions of: 410–450 °C, 0.25–1 hr−1, 160 bar, 1500 Nm3/m3 of H2 to oil ratio, and 500 ppm catalyst (Mo-octoate). A five-lump model with ten reaction pathways was adopted to describe the hydrocracking kinetics, while the hydrotreating reactions were modeled by the power-law approach. The kinetic parameters were estimated considering the change in liquid density with reaction time. The kinetic model predicted product yields and concentrations with an average error of less than 10%. As for the hydrocracking reaction, it was demonstrated that the secondary cracking of VGO mainly produced MD at high temperature and the high conversion of RES. As for hydrotreating, it was confirmed that asphaltene conversion proceeded to increase the removal level of other impurities. Finally, a hydrogen consumption rate model was proposed based on HCK and HDT, which provides consistent information for further uses in reactor modeling and process modeling.



中文翻译:

分散催化剂在CSTR中重油的加氢裂化和加氢处理反应动力学

410-450℃,0.25-1小时:真空残基的淤浆相加氢裂化的动力学模型的条件下提出-1牛米,160巴,1500 3 /米3 h的2油比和500 ppm催化剂(辛酸)。采用具有十个反应路径的五集模型来描述加氢裂化动力学,而加氢处理反应则通过幂律法进行建模。考虑液体密度随反应时间的变化来估算动力学参数。动力学模型预测产品的收率和浓度,平均误差小于10%。关于加氢裂化反应,证明了VGO的二次裂化主要在高温和RES的高转化率下产生MD。对于加氢处理,已证实沥青质转化进行以增加其他杂质的去除水平。最后,提出了基于HCK和HDT的氢耗率模型,

更新日期:2020-09-29
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