Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2020-09-28 , DOI: 10.1080/10426507.2020.1825432 Duygu Palabıyık 1 , Ceylan Mutlu Balcı 1 , Serap Beşli 1
Abstract
The aminolysis reactions of hexachlorocyclotriphosphazene, N3P3Cl6 (1a) and di-spirodioxy cyclotriphosphazene derivative N3P3Cl2[OCH2(CF2)2CH2O]2 (1b) with 1-benzyl-1H-pyrazol-3-amine (2) were investigated. Two new pyrazole amine substituted cyclotriphosphazene derivatives (3a, b) were obtained. Both compounds (3a, b) have been characterized by elemental analysis, MALDI-TOF mass spectrometry, 1H, and 31P NMR spectroscopy. The molecular and crystal structures of 3a and 3b were confirmed by single crystal X-Ray crystallography. Hirshfeld surface analyses of the crystal structures of 3a and 3b were investigated to determine the remarkable interactions between the molecules and the packing nature of the molecules in the crystals.
中文翻译:
吡唑胺取代的环三磷腈的合成:光谱和晶体学表征
摘要
六氯环三磷腈,N 3 P 3 Cl 6(1a)和二螺二氧基环三磷腈衍生物N 3 P 3 Cl 2 [OCH 2(CF 2)2 CH 2 O] 2(1b)与1-苄基-1H-的氨解反应研究了吡唑-3-胺(2)。获得了两种新的吡唑胺取代的环三磷腈衍生物(3a,b)。两种化合物(3a,b通过元素分析,MALDI-TOF质谱,1 H和31 P NMR光谱进行表征。通过单晶X射线晶体学证实了3a和3b的分子和晶体结构。对3a和3b的晶体结构进行了Hirshfeld表面分析,以确定分子之间的显着相互作用以及分子在晶体中的堆积性质。