ABSTRACT

On 15 high nitrogen and three polynitrated polyazaarenes (including six azido-derivatives), the paper demonstrates the relations between their impact sensitivities (E_dr) on the one hand and the volume heats (ρQ_max) or a representative of detonation pressure (ρD²) of their explosion or their enthalpies of formation (ΔH_form) on the other. The semi-logarithmic subrelations between the E_dr and ρQ_max values are limited by the mechanism of primary fission. While the mentioned relations between E_dr and ρQ_max values for azido derivatives predominantly show the expected course, in the case of the remaining high-nitrogen EMs, the opposite is the case, i.e., an increase in ρQ_max values corresponds to a decrease in impact sensitivity. The same is valid for ρD² values as an independent variable. Taking the energy content of the studied EM molecules, represented by ΔH_form values, instead of the heat of explosion, yields unambiguous semilogarithmic relations, according to which the growth of the ΔH_form values increases impact sensitivity. The results obtained indicate that it is necessary to distinguish between the influences of the performance and the energetic content of high-nitrogen energetic materials on their initiation reactivity.

摘要

对 15 种高氮和 3 种多硝化聚氮杂芳烃（包括 6 种叠氮衍生物），本文论证了它们的冲击敏感性（E _dr）一方面与体积热（ρQ _max）或代表爆轰压力（ρD ² ) 它们的爆炸或它们的形成焓 ( ΔH_形式) 在另一个上。E _dr和ρQ_最大值之间的半对数子关系受到初级裂变机制的限制。虽然E _dr和ρQ _max之间的关系叠氮基衍生物的值主要显示预期的过程，在剩余的高氮 EM 的情况下，情况正好相反，即ρQ_最大值的增加对应于冲击灵敏度的降低。这同样适用于作为自变量的ρD ²值。取所研究的 EM 分子的能量含量，以ΔH_形式值表示，而不是爆炸热，产生明确的半对数关系，根据该关系，ΔH_形式的增长值会增加影响敏感性。所得结果表明，有必要区分高氮含能材料的性能和含能量对其引发反应性的影响。