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Multiferroic Properties of Pure and Transition Metal Doped LaFeO3 Nanoparticles
Physica Status Solidi (B) - Basic Solid State Physics ( IF 1.5 ) Pub Date : 2020-09-26 , DOI: 10.1002/pssb.202000482
Iliana N. Apostolova 1 , Angel T. Apostolov 2 , Steffen Trimper 3 , Julia M. Wesselinowa 4
Affiliation  

The size, doping concentration, and magnetic field dependences of the magnetization M and the real part of the dielectric function ε ' in doped LaFe 1 x M x O 3 nanoparticles (NPs) are studied using a microscopic model. Although M increases, ε decreases with decreasing NPs size in pure LaFeO 3 . Doping with different ions causes different strain which modifies the exchange interaction. As a consequence, M and ε grow with increasing Mn or Zn ion doping, whereas both quantities decrease by doping with Ti or Al ions. The magneto‐dielectric coefficient increases with an applied external magnetic field and Mn doping concentration in pure and Mn‐doped LaFeO3 indicating that pure and doped LaFeO 3 NPs exhibit a multiferroic behavior. A microscopic model is proposed to study multiferroic Bi2NiMnO6 thin films.

中文翻译:

掺杂纯金属和过渡金属的LaFeO3纳米粒子的多铁性

磁化强度M和介电函数实部的大小,掺杂浓度和磁场依赖性 ε ' 在掺杂 镧铁 1个 - X 中号 X Ø 3 使用显微镜模型研究了纳米颗粒(NPs)。虽然M增加了 ε 随NPs尺寸的减小而减小 氧化铁 3 。掺杂不同的离子会导致不同的应变,从而改变交换相互作用。结果,M ε Mn或Zn离子的掺杂量会增加,而Ti或Al离子的掺杂量都会减少。磁介电系数随所施加的外部磁场和纯掺杂Mn掺杂的LaFeO 3中Mn掺杂浓度的增加而增加,表明纯掺杂 氧化铁 3 NP表现出多铁性行为。提出了用于研究多铁性Bi 2 NiMnO 6薄膜的微观模型。
更新日期:2020-09-26
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