Biomimetic systems involving sequential redox reactions in glycolysis – the sulfur effect,Chemical Communications

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Biomimetic systems involving sequential redox reactions in glycolysis – the sulfur effect
Chemical Communications ( IF 4.3 ) Pub Date : 2020-09-25 , DOI: 10.1039/d0cc05185c
Narihito Ogawa _{1,

2,

3,

4} , Sei Furukawa _{4,

5,

6,

7} , Yuya Kosugi _{1,

2,

3,

4} , Takayuki Takazawa _{1,

2,

3,

4} , Nobuhiro Kanomata _{4,

5,

6,

7}

Affiliation

Magnesium hemithioacetates were used as model cysteine compounds to mimic natural hemithioacetals, and their biomimetic oxidation reactions using a model NAD⁺ compound were investigated. Cyclic hemithioacetate was found to be the best substrate for the reaction with the model NAD⁺ compound, which gave the corresponding NADH analog in excellent yield.

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