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Isomeric ammonio derivatives of nido-carborane 3- and 10-H3N-7,8-C2B9H11
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2020-09-25 , DOI: 10.1080/10426507.2020.1804148 Sergey A. Anufriev 1 , Akim V. Shmal’ko 1 , Marina Yu. Stogniy 1 , Kyrill Yu. Suponitsky 1 , Igor B. Sivaev 1
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2020-09-25 , DOI: 10.1080/10426507.2020.1804148 Sergey A. Anufriev 1 , Akim V. Shmal’ko 1 , Marina Yu. Stogniy 1 , Kyrill Yu. Suponitsky 1 , Igor B. Sivaev 1
Affiliation
Abstract Structure of 3-ammonio derivative of nido-carborane 3-NH3-7,8-C2B9H11 was determined by single crystal X-ray diffraction. The isomeric 10-ammonio derivative 10-NH3-7,8-C2B9H11 was prepared by the treatment of the corresponding ethylnitrilium derivative 10-EtC≡N-7,8-C2B9H11 with hydrazine hydrate in acetonitrile. GRAPHICAL ABSTRACT
中文翻译：
nido-carborane 3-和10-H3N-7,8-C2B9H11的异构氨衍生物
摘要 通过单晶X射线衍射确定了nido-carborane 3-NH3-7,8-C2B9H11的3-氨基衍生物的结构。通过在乙腈中用水合肼处理相应的乙腈衍生物 10-EtC≡N-7,8-C2B9H11 来制备异构的 10-氨衍生物 10-NH3-7,8-C2B9H11。图形概要
更新日期：2020-09-25
中文翻译：
nido-carborane 3-和10-H3N-7,8-C2B9H11的异构氨衍生物
摘要 通过单晶X射线衍射确定了nido-carborane 3-NH3-7,8-C2B9H11的3-氨基衍生物的结构。通过在乙腈中用水合肼处理相应的乙腈衍生物 10-EtC≡N-7,8-C2B9H11 来制备异构的 10-氨衍生物 10-NH3-7,8-C2B9H11。图形概要
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