Abstract Tertiary alkyl, aryl or amino phosphines PR3 (R = Me, nBu, C2H4CN, NEt2) and the bis(phosphine) POP were allowed to react with fluoroiodomethane to produce fluoromethyl phosphonium salts. New crystal structures of forming fluoromethyl phosphonium salts [R3PCH2F]I with R = Me, C2H2CN and NEt2 were obtained and gave additional information of the nearly unknown P-CH2F moiety. The toxicity of the water soluble salt [Me3PCH2F]I was investigated compared to the biocide THPS. GRAPHICAL ABSTRACT

中文翻译：

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使用生物等排 CH2F 部分调节基于鏻的杀菌剂的毒性

摘要 使叔烷基、芳基或氨基膦 PR3（R = Me、nBu、C2H4CN、NEt2）和双（膦）POP 与氟碘甲烷反应生成氟甲基鏻盐。获得了形成氟甲基鏻盐 [R3PCH2F]I 的新晶体结构，其中 R = Me、C2H2CN 和 NEt2，并提供了几乎未知的 P-CH2F 部分的额外信息。与杀生物剂 THPS 相比，研究了水溶性盐 [Me3PCH2F]I 的毒性。图形概要