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Advances in Henry Reaction: A Versatile Method in Organic Synthesis
Mini-Reviews in Organic Chemistry ( IF 1.9 ) Pub Date : 2020-05-01 , DOI: 10.2174/1570193x16666190214150144
Nidhi Singh 1 , Jaya Pandey 1
Affiliation  

Henry reaction is an important reaction employing carbonyls which furnishes β-nitro alcohol, nitroalkene, α-nitro ketones, β-amino alcohol as products and byproducts that may be transfigured as building blocks for other synthetic reactions. This paper focuses on various synthetic routes for Henry reaction, a versatile reaction of high significance in organic synthesis. The paper discusses the chemistry and plausible products of the reaction, along with the various available synthetic routes for the same, ranging from classical conventional methods to modern methods of green chemistry trends. Use of various catalysts as rate enhancer as well as use of various catalysts as enantioselective frontman for stereoselective reactions, have been described in this work.



中文翻译:

亨利反应的进展:一种有机合成的通用方法

亨利反应是一种重要的反应,利用羰基化合物提供β-硝基醇,硝基烯烃,α-硝基酮,β-氨基醇作为产物和副产物,这些产物可能会被转化为其他合成反应的基础。本文重点研究亨利反应的各种合成途径,这是有机合成中具有重要意义的通用反应。本文讨论了反应的化学和可能的产物,以及从传统的常规方法到现代绿色化学趋势方法的各种可用合成路线。在这项工作中已经描述了使用各种催化剂作为速率增强剂以及使用各种催化剂作为对映选择性主旋体。

更新日期:2020-05-01
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