Abstract

The composition of sulfur-bound compounds of asphaltic–resinous substances of bitumen from oil shale sampled from the Dmitrievskoe deposit (Kuzbass) has been studied using the technique of selective chemical destruction. It has been shown that the structure of asphaltenes and resins contains moieties represented by alkanes, phenylalkanes, phenanthrenes, fluoranthenes, pyrenes, and methyl esters of aliphatic acids that are linked to each other or to the polycondensed core of their molecules through alkyl sulfide bridges. A distinctive feature of asphaltene molecules is the presence of S-bound phenyl- and naphthene-substituted aromatic hydrocarbons and aromatic oxygen-containing compounds in their composition.

中文翻译：

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油页岩有机质高分子量杂原子组分的组成

摘要

从Dmitrievskoe矿床（库兹巴斯）取样的油页岩中，沥青质沥青质树脂的硫结合化合物的组成已通过选择性化学破坏技术进行了研究。已经表明，沥青质和树脂的结构包含以烷烃，苯基链烷烃，菲，芴、,和脂族脂肪酸的甲基酯为代表的部分，它们通过烷基硫化物桥彼此或与其分子的缩聚核相连。沥青质分子的一个显着特征是在其组成中存在S-结合的苯基和萘基取代的芳族烃以及含芳族含氧化合物。