International Journal of Biological Macromolecules ( IF 7.7 ) Pub Date : 2020-09-23 , DOI: 10.1016/j.ijbiomac.2020.09.183 Ricardo Camacho-Muñoz , Héctor Samuel Villada-Castillo , Jose Fernando Solanilla-Duque
TPS/MA/PLA is a blend of thermoplastic starch (TPS) and polylactic acid (PLA) compatibilized by maleic anhydride (MA) that can be a substitute for petro-based plastics in certain applications. At the end of its life, this material must be properly disposed in treatment systems such as composting or anaerobic digestion. The biodegradability of TPS/MA/PLA, PLA, TPS and the non-compatible mixture (TPS/PLA) was evaluated in a slurry thermophilic anaerobic digestion system (STAD) according to ISO 13975-2012 standard. The anaerobic inoculum was prepared from cow manure and the organic fraction of municipal solid waste. After 31 days of incubation, the pure PLA exhibited a 12-day lag phase and 40.41% of biodegradability. TPS, TPS/PLA and TPS/MA/PLA did not exhibit lag phase and reached 92.11%, 65.48% and 64.82% of biodegradation respectively. The slow degradation rate of PLA is attributed to its high glass transition temperature and crystallinity. In TPS/MA/PLA and TPS/PLA, about 50% of PLA and 13% to 10% of the TPS remains undegraded and MA did not affect the biodegradation of TPS/MA/PLA compared to TPS/PLA. Results suggest that, in very short retention times STAD systems, PLA based materials could not exhibit enough biodegradability.
中文翻译:
马来酸酐相容的聚乳酸/淀粉共混物在浆液嗜热条件下的厌氧生物降解
TPS / MA / PLA是热塑性淀粉(TPS)和聚乳酸(PLA)的混合物,并与马来酸酐(MA)相容,可以在某些应用中替代石油基塑料。在其使用寿命结束时,必须将该材料正确处理在堆肥或厌氧消化等处理系统中。根据ISO 13975-2012标准,在浆液嗜热厌氧消化系统(STAD)中评估了TPS / MA / PLA,PLA,TPS和不相容混合物(TPS / PLA)的生物降解能力。厌氧接种物由牛粪和城市固体废物的有机部分制成。孵育31天后,纯PLA表现出12天的滞后阶段和40.41%的生物降解性。TPS,TPS / PLA和TPS / MA / PLA没有出现滞后现象,分别达到92.11%,65.48%和64.82%的生物降解率。PLA的缓慢降解速率归因于其较高的玻璃化转变温度和结晶度。在TPS / MA / PLA和TPS / PLA中,与TPS / PLA相比,约50%的PLA和13%至10%的TPS保持未降解,并且MA不影响TPS / MA / PLA的生物降解。结果表明,在保留时间非常短的STAD系统中,基于PLA的材料无法表现出足够的生物降解性。