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3-Amino-4-(1-amino-2-cyanovinyl)furazans: synthesis and cyclization
Chemistry of Heterocyclic Compounds ( IF 1.4 ) Pub Date : 2020-09-23 , DOI: 10.1007/s10593-020-02781-7
Kirill V. Strizhenko , Leonid S. Vasil’ev , Kyrill Yu. Suponitsky , Aleksei B. Sheremetev

It was shown that 3-amino-4-cyanofurazan easily condenses with malononitrile and ethyl cyanoacetate in the presence of bases, forming polyfunctional enaminonitriles – precursors in the synthesis of pyrazoles and annulated derivatives of furazano[3,4-b]pyridines and furazano[3,4-b]pyrimidines.



中文翻译:

3-Amino-4-(1-amino-2-cyanovinyl)furazans:合成和环化

结果表明,在碱存在下,3-amino-4-cyanofurazan容易与丙二腈和氰基乙酸乙酯缩合,形成多官能的烯腈-吡唑和呋喃并[3,4- b ]吡啶和呋喃并[ 3,4- b ]嘧啶。

更新日期:2020-09-23
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