Sb-SnO₂/Ti electrode membrane was prepared by loading Sb-SnO₂ polymer precursor on the original Ti substrate electrode membrane, then MnO_x sol was coated on the surface of Sb-SnO₂/Ti to obtain MnO_x/Sb-SnO₂/Ti composite electrode membrane via sol–gel method. Compared with MnO_x/Ti, the new crystal form and solid solution were identified in MnO_x/Sb-SnO₂/Ti due to the presence of Sb-SnO₂ interlayer, which was beneficial to improve the electrochemical performance of MnO_x/Ti. In particular, the specific surface area of MnO_x/Ti was increased by inserting Sb-SnO₂ interlayer. Electrocatalytic membrane reactor (ECMR) is assembled with the electrode membrane as the anode and the stainless-steel mesh as the cathode for phenolic wastewater treatment. pH value and Sb-SnO₂-loading amount had great effect on the energy consumption of ECMR. When the current density, residence time and Sb-SnO₂ loading were 0.9 mA/cm², 15 min and 3.4 wt%, the phenol and COD degradation rate of ECMR with MnO_x/Sb-SnO₂/Ti reached 98.98% and 89.38%, whereas were 80.56% and 71.12% in case of MnO_x/Ti, respectively.

通过将Sb-SnO ₂聚合物前驱体装载到原始的Ti基体电极膜上制备Sb-SnO ₂ / Ti电极膜，然后在Sb-SnO ₂ / Ti表面涂覆MnO _x溶胶以获得MnO _x / Sb-SnO ₂ / Ti复合电极膜通过溶胶-凝胶法。与MnO _x / Ti相比，由于存在Sb-SnO ₂中间层，因此在MnO _x / Sb-SnO ₂ / Ti中鉴定出新的晶型和固溶体，有利于提高MnO _x / Ti的电化学性能。。特别是MnO _x的比表面积通过插入Sb-SnO ₂中间层来增加/ Ti 。电催化膜反应器（ECMR）以电极膜为阳极，不锈钢网为阴极，用于酚醛废水处理。pH值和Sb-SnO _2的负载量对ECMR的能耗有很大影响。当电流密度，停留时间和Sb的SnO ₂装载分别为0.9毫安/厘米²，15分钟，3.4重量％，ECMR的苯酚和COD降解率的MnO _X /锑的SnO ₂ / Ti的达到98.98％和89.38 ％，而在MnO _x / Ti的情况下分别为80.56％和71.12％。