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Synthesis of a novel Type-II In2S3/Bi2MoO6 heterojunction photocatalyst: Excellent photocatalytic performance and degradation mechanism for Rhodamine B
Separation and Purification Technology ( IF 8.1 ) Pub Date : 2020-09-22 , DOI: 10.1016/j.seppur.2020.117758
Hao Cui , Sheying Dong , Kangkang Wang , Mingsha Luan , Tinglin Huang

Indium sulfide (In2S3) has been proven to be a photocatalyst with giant potential, but its photocatalytic activity is still severely limited by the disadvantages such as the sluggish charge separation. Herein, a series of novel photocatalysts with Type-II In2S3/bismuth molybdate (Bi2MoO6) heterostructures were handily fabricated through hydrothermal route. Under 90 minutes of visible light illumination, all the In2S3/Bi2MoO6 heterostructures demonstrated more splendid activity for Rhodamine B (RhB) degradation than pure In2S3 and Bi2MoO6 at low catalyst dose (0.2 g/L). Especially, the IB-2 displayed the highest degradation efficiency (88.2 %) and the fastest degradation velocity (k=0.02826 min-1), where its k value was nearly 2.48 and 6.51 times stronger than that of In2S3 and Bi2MoO6, respectively. More importantly, the removal efficiency was still above 81.4 % after 4 cycles. The reinforced photocatalytic activity was ascribed to the increase of active sites, extending of visible light response and forceful transfer of carriers. Meanwhile, the Type-II charge transfer mechanism was evidenced by the result of radical trapping test. As a complement, this work offers new insights for establishing efficient and stable In2S3-based composite photocatalysts.



中文翻译:

新型II型In 2 S 3 / Bi 2 MoO 6异质结光催化剂的合成:罗丹明B的优异光催化性能和降解机理

硫化铟(In 2 S 3)已被证明是具有巨大潜力的光催化剂,但是其光催化活性仍然受到电荷分离缓慢等缺点的严重限制。在此,通过水热法容易地制备了一系列具有II型In 2 S 3 /钼酸铋(Bi 2 MoO 6)异质结构的新型光催化剂。在90分钟的可见光照射下,与纯In 2 S 3相比,所有In 2 S 3 / Bi 2 MoO 6异质结构均表现出对罗丹明B(RhB)降解更出色的活性。和低催化剂剂量(0.2 g / L)的Bi 2 MoO 6。特别是,IB-2表现出最高的降解效率(88.2%)和最快的降解速度(k = 0.02826 min -1),其k值比In 2 S 3和Bi 2的k值分别高近2.48和6.51倍。MoO 6, 分别。更重要的是,经过4个循环后,去除效率仍高于81.4%。增强的光催化活性归因于活性位点的增加,可见光响应的扩展和载体的强制转移。同时,自由基捕获测试的结果证明了II型电荷转移机制。作为补充,这项工作为建立高效,稳定的基于2 S 3的复合光催化剂提供了新的见识。

更新日期:2020-09-22
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