Phosphotungstic acid (H₃PW₁₂O₄₀, HPW) exhibits a good desulfurization performance towards the oxidative desulfurization (ODS) of oil-derived fuels. However, it presents two drawbacks: a small specific surface area and poor recovery. In this work, HPW was loaded on the support UiO-66 with a stable structure and large specific surface area, and a family of HPW@UiO-66 catalysts was prepared. Based on the structure and property analyses of powder FT-IR, ICP-OES, XRD, SEM, TG and BET, 0.5-HPW@UiO-66 with defects possessed a high crystallinity, regular morphology, stable structure and dispersed HPW clusters. The removal efficiency of DBT reached 100% and was maintained at 94.70% after 12 times of repeated use under the optimal reaction conditions. The results showed that the catalytic performance of HPW@UiO-66 catalyst for model oil desulfurization was improved when the defects existed.

磷钨酸（H ₃ PW ₁₂ O ₄₀，HPW）对源自石油的燃料的氧化脱硫（ODS）表现出良好的脱硫性能。但是，它具有两个缺点：比表面积小和回收率差。在这项工作中，将HPW负载在具有稳定结构和大比表面积的载体UiO-66上，并制备了一系列HPW @ UiO-66催化剂。根据粉末FT-IR，ICP-OES，XRD，SEM，TG和BET的结构和性能分析，具有缺陷的0.5-HPW@UiO-66具有较高的结晶度，规则的形貌，稳定的结构和分散的HPW团簇。在最佳反应条件下重复使用12次后，DBT的去除效率达到100％，并保持在94.70％。