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Photocatalytic Treatment of Waste Water from Rice Husk Alkaline Hydrolysate
Rice Science ( IF 4.8 ) Pub Date : 2019-06-26 , DOI: 10.1016/j.rsci.2018.10.008
Olga D. Arefieva , Marina S. Vasilyeva , Ekaterina V. Ermolenko , Anastasiia V. Bychkova

We carried out photocatalytic treatment of a lignin-free solution of rice husk alkaline hydrolysate [pH of 2, chemical oxygen demand (COD) of 12.8 g/L] using photo-Fenton process in the ultraviolet (UV, wavelength of 365 nm) and visible spectrum. Oxidation of lignin was performed at a constant mass ratio of COD:H2O2 as 1:2 and Fe2+ concentration of 80 mg/L. It was established that for the destruction of alkaline lignin, exposure to visible or UV radiation was necessary. Decolorization efficiency of a lignin-free solution depends on the dilution rate of the solution. The advanced oxidative photo-Fenton process (UV/Н2О2/Fe2+) made it possible to reduce the color of lignin-free solution at a dilution ratio of 1:5 by 94% of decolorization efficiency, 87% of phenolic compound and 79% of COD. With the help of gas chromatography, the products of lignin destruction were low-toxic and usable.



中文翻译:

稻壳碱水解产物的光催化处理。

我们在紫外线(UV,波长为365 nm)和紫外光下使用光芬顿法对稻壳碱性水解产物[pH为2,化学需氧量(COD)为12.8 g / L]的无木质素溶液进行了光催化处理。可见光谱。木质素的氧化以COD:H 2 O 2的质量比为1:2且Fe 2+浓度为80 mg / L进行。已经确定,为了破坏碱性木质素,必须暴露于可见光或紫外线辐射。不含木质素的溶液的脱色效率取决于溶液的稀释率。先进的氧化光芬顿处理(UV /Н 2 О 2 /铁2+)可以以1:5的稀释比将无木质素溶液的颜色降低94%的脱色效率,87%的酚类化合物和79%的COD。借助气相色谱,破坏木质素的产品低毒且可用。

更新日期:2019-06-26
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