Enantioselective Aza‐Diels Alder reaction catalyzed by clay supported Schiff base complex†,Journal of Heterocyclic Chemistry

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Enantioselective Aza‐Diels Alder reaction catalyzed by clay supported Schiff base complex†
Journal of Heterocyclic Chemistry ( IF 2.0 ) Pub Date : 2020-09-20 , DOI: 10.1002/jhet.4155
V Kannan ₁ , K Sreekumar ₂

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Clay supported catalysts based on 2‐ hydroxy naphthaldehyde and amino acids, their copper and titanium complexes have been described. The catalysts were found to be active toward the synthesis of pyrano‐, furanoquinolines through Aza‐Diels Alder reaction. The catalysts gave good yield and high enantioselectivity. The catalysts were environmentally friendly, economical, synthetically robust and reusable.

中文翻译：

粘土负载的席夫碱配合物催化对映选择性的Aza-Diels Alder反应†

已经描述了基于2-羟基萘醛和氨基酸的粘土负载型催化剂，以及它们的铜和钛络合物。发现该催化剂对通过Aza-Diels Alder反应合成吡喃并呋喃喹啉具有活性。该催化剂具有良好的产率和高的对映选择性。该催化剂环保，经济，合成坚固且可重复使用。

更新日期：2020-09-20

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