A novel ladder‐type coordination polymer (CP), poly[(μ‐4,4′‐bipyridine‐κ²N:N′){μ‐4‐[(4‐carboxybenzyloxy)methyl]benzoato‐κO}silver(I)](Ag—Ag), [Ag(C₁₆H₁₃O₅)(C₁₀H₈N₂)]_n or [Ag(HL)(4,4′‐bpy)]_n {H₂L is 4,4′‐[oxybis(methylene)]dibenzoic acid and 4,4′‐bpy is 4,4′‐bipyridine}, was synthesized using hydrothermal methods. The complex was characterized by IR spectroscopy, elemental analysis and single‐crystal X‐ray diffraction, and is a ladder‐type CP which exhibits an obvious Ag—Ag interaction. The legs of the ladder are formed by parallel 4,4′‐bipy ligands and silver ions, and the rungs are constructed by Ag—Ag interactions. A Hirshfeld surface analysis was carried out and is discussed in detail. The complex also displays favourable fluorescence properties.

中文翻译：

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一种具有4,4'-联吡啶和4-[（4-羧基苄氧基）甲基]苯甲酸酯配体的新型梯型银（I）配位聚合物：合成，晶体结构，荧光性质和Hirshfeld表面分析

一种新颖的阶梯型配位聚合物（CP），聚[（μ-4,4'-联吡啶κ ² Ñ：Ñ '）{μ-4 - [（4- carboxybenzyloxy）甲基] benzoato-κ Ö }银（ I）]（Ag - Ag），[Ag（C ₁₆ H ₁₃ O ₅）（C ₁₀ H ₈ N ₂）] _n或[Ag（H L）（4,4'-bpy）] _n {H ₂ L采用水热法合成了4,4'-[氧双（亚甲基）]二苯甲酸和4,4'-bpy为4,4'-联吡啶}。该复合物通过红外光谱，元素分析和单晶X射线衍射进行表征，是一种梯形CP，具有明显的Ag-Ag相互作用。梯子的腿由平行的4,4'-联吡啶配体和银离子形成，梯级由Ag-Ag相互作用构成。进行了Hirshfeld表面分析，并进行了详细讨论。该配合物还显示出有利的荧光性质。