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Activated charcoal as an effective additive for alkaline and acidic hydrolysis of esters in water
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2020-09-19 , DOI: 10.1016/j.tetlet.2020.152467
Kiyoshi Tanemura , Taoufik Rohand

Activated charcoal largely enhanced the rates of the alkaline hydrolysis of methyl, ethyl, and n-propyl esters in aqueous 1.5 M NaOH solution to give the corresponding carboxylic acids in excellent yields. The acidic hydrolysis of methyl, ethyl, and n-propyl esters in aqueous 3 M H2SO4 solution was accelerated by the addition of activated charcoal to afford the corresponding carboxylic acids in good yields.



中文翻译:

活性炭作为水中酯类的碱和酸水解的有效添加剂

活性炭在1.5 M NaOH水溶液中大大提高了甲酯,乙酯和丙酯的碱性水解速度,从而以极高的收率得到了相应的羧酸。通过在活性炭中加入3 MH 2 SO 4水溶液,可以加速甲基,乙基和丙基酯的酸性水解,从而以高收率得到相应的羧酸。

更新日期:2020-10-12
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