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SiC/SiC mini-composites with yttrium disilicate fiber coatings: Oxidation in steam
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-09-18 , DOI: 10.1016/j.jeurceramsoc.2020.09.033
Emmanuel E. Boakye , Thomas S. Key , Pavel Mogilevsky , Samuel J. Opeka , Randall Corns , Randall S. Ha , Michael K. Cinibul

Solutions of YPO4 were used to precipitate YPO4 on pre-oxidized Hi-Nicalon-S SiC fibers. Tows of the coated fibers were then infiltrated with a preceramic polymer loaded with SiC particles to form mini-composites. During pyrolysis of the matrix, SiO2 and YPO4 on the fibers reacted and formed a Y2Si2O7 fiber matrix interphase. Mini-composites were exposed to steam at 1000 °C for 10, 50, and 100 h, tensile tested, and the effect of oxidation in steam on the functionality of the Y2Si2O7 fiber coating was investigated. The minicomposites oxidized at 1000 °C for 10 h retained 100 % of their unoxidized strength, and those oxidized for 50 and 100 h retained 92 % and 90 % of unoxidized strength, respectively. Strength retention and fiber pullout in both unoxidized and oxidized minicomposites suggests that the Y2Si2O7 interphase was effective in maintaining a weak fiber-matrix interface.



中文翻译:

具有二硅酸钇纤维涂层的SiC / SiC微型复合材料:蒸汽中的氧化

使用YPO 4溶液在预氧化的Hi-Nicalon-S SiC纤维上沉淀YPO 4。然后,用负载有SiC颗粒的陶瓷前聚合物渗透涂层纤维束,以形成微复合材料。在基体热解期间,纤维上的SiO 2和YPO 4反应并形成Y 2 Si 2 O 7纤维基体中间相。将微型复合材料暴露于1000°C的蒸汽中10、50和100 h,进行拉伸测试,以及蒸汽中氧化对Y 2 Si 2 O 7官能度的影响研究了纤维涂层。在1000°C氧化10 h的微复合材料保留其未氧化强度的100%,在50和100 h氧化的微复合材料分别保留92%和90%的未氧化强度。在未氧化和已氧化的微复合材料中,强度保持率和纤维拉出性均表明,Y 2 Si 2 O 7界面有效地维持了弱的纤维-基质界面。

更新日期:2020-09-18
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