Photocatalytic CO₂ reduction into fuels has been an attractive research topic. Herein, Ag and TiO₂ nanoparticles co-loaded zeolite TS-1 (Ag-TiO₂/TS-1) were synthesized by the ion-exchange and subsequently in-situ photodeposition method. The obtained Ag-TiO₂/TS-1 sample has a high surface area and rich Ti³⁺-V_o defects and as well as highly dispersed Ag nanoparticles. As expected, the sample Ag-TiO₂/TS-1 not only shows high CO₂ adsorption capacity, but also improves the separation efficiency of photogenerated electron-hole pairs. As a result, only CO and CH₄ can be detected on the sample Ag-TiO₂/TS-1 in the photocatalytic CO₂ conversion, and the competing H₂ evolution can be completely suppressed, suggestive of its high selectivity. The super photocatalytic activity toward CO₂ reduction can be ascribed to the synergistic effect among highly dispersed Ag nanoparticle, the support zeolite TS-1 and TiO₂ with highly exposed {101} planes.

光催化将CO ₂还原为燃料一直是一个有吸引力的研究主题。在此，通过离子交换和随后的原位光沉积法合成了负载有TS-1沸石的Ag和TiO ₂纳米颗粒（Ag-TiO ₂ / TS-1）。所得的Ag-TiO ₂ / TS-1样品具有高的表面积和丰富的Ti ³⁺ -V _o缺陷以及高度分散的Ag纳米颗粒。不出所料，样品Ag-TiO ₂ / TS-1不仅显示出高的CO ₂吸附能力，而且提高了光生电子-空穴对的分离效率。结果，在样品Ag-TiO ₂上只能检测到CO和CH _4。/ TS-1在光催化CO ₂转化中以及竞争性H _2的释放可以被完全抑制，这表明它具有很高的选择性。对CO ₂还原的超光催化活性可以归因于高度分散的Ag纳米颗粒，具有高度暴露的{101}面的载体沸石TS-1和TiO ₂之间的协同作用。