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Control of the phase formation process in solutions of anionic polyelectrolyte—cationic surfactant complexes in a microfluidic channel
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2020-08-01 , DOI: 10.1007/s11172-020-2920-6
A. N. Bezrukov , Yu. G. Galyametdinov

The process of phase formation in solutions of polyacrylic acid and cetyltrimethylammonium bromide was studied in microfluidic channels with a characteristic size of 100–200 µm. The system of convection—diffusion—reaction equations was solved to develop an association model in polyelectrolyte—surfactant solutions in a microchannel with the laminar flow of the reactants. The phase formation conditions in the microchannel volume were considered. The recommendations for control of the phase behavior in the microchannel were proposed, as well as for the design and operation mode of microfluidic devices used for the synthesis of polymer—surfactant complexes and characterization of association in polyelectrolyte—surfactant solutions.

中文翻译:

微流体通道中阴离子聚电解质-阳离子表面活性剂复合物溶液中相形成过程的控制

在特征尺寸为 100-200 µm 的微流体通道中研究了聚丙烯酸和十六烷基三甲基溴化铵溶液中的相形成过程。解决了对流-扩散-反应方程的系统,以开发聚电解质-表面活性剂溶液在微通道中与反应物层流的结合模型。考虑了微通道体积中的相形成条件。提出了控制微通道中相行为的建议,以及用于合成聚合物-表面活性剂复合物和聚电解质-表面活性剂溶液中结合表征的微流体装置的设计和操作模式。
更新日期:2020-08-01
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